English

Rotational coherences in O$_2^+$ following strong-field ionization

Atomic Physics 2025-07-10 v1 Atomic and Molecular Clusters Optics

Abstract

We investigate the wave packet that remains bound in the ground and excited cationic states of oxygen after strong-field ionization by an intense 800-nm pulse. Much weaker probe pulses (800 or 264 nm) are used to dissociate these still-bound cations. The momentum distribution of O+^+ is measured as a function of pump-probe delay and Fourier-transformed to obtain kinetic-energy-dependent and rotational-state-resolved quantum beat spectra. The sub-cm1^{-1} resolution of the Fourier transform allows unambiguous identification of the electronic, vibrational, and rotational states populated by the pump and then dissociated by the probe. Although strong-field ionization is expected to populate the lower-lying X2ΠgX^2\Pi_g and a4Πua^4\Pi_u states more effectively than the b4Σgb^4\Sigma^{-}_g state, a wave packet in the X2ΠgX^2\Pi_g state is seen only with the 264-nm probe and only weak signatures of the a4Πua^4\Pi_u states are found with either probe. The experiment confirms the role of the resonant coupling between the b4Σgb^4\Sigma^{-}_g and a4Πua^4\Pi_u states by the 800 nm pulses [Xue \textit{et al.}, Phys. Rev. A 97, 043409 (2018)] and reveals the importance of rovibrational excitation in determining the momentum distribution of the O+^+ fragments. The strong X2ΠgX^2\Pi_g state contribution observed with the 264-nm probe also shows the importance of resonant coupling in the probe pulse. The sub-cm1^{-1} resolution also resolves spin-orbit splitting in both the X2ΠgX^2\Pi_g and a4Πua^4\Pi_u state wave packets.

Keywords

Cite

@article{arxiv.2507.06680,
  title  = {Rotational coherences in O$_2^+$ following strong-field ionization},
  author = {Huynh Van Sa Lam and Tomthin Nganba Wangjam and Vinod Kumarappan},
  journal= {arXiv preprint arXiv:2507.06680},
  year   = {2025}
}

Comments

7 figures