English

Rigorous description of exchange-correlation energy of many-electron systems

Materials Science 2007-12-07 v1 Strongly Correlated Electrons

Abstract

With the eigenfunctional theory, we study a general interacting electron system, and give a rigorous expression of its ground state energy which is composed of two parts, one part is contributed by the non-interacting electrons, and another one is represented by the correlation functions that are controlled by the electron correlation. Moreover, according to the rigorous expression of the ground state energy, an effective method beyond the local density approximation of the density functional theory is proposed.

Keywords

Cite

@article{arxiv.0712.0865,
  title  = {Rigorous description of exchange-correlation energy of many-electron systems},
  author = {Yu-Liang Liu},
  journal= {arXiv preprint arXiv:0712.0865},
  year   = {2007}
}

Comments

9pages

R2 v1 2026-06-21T09:51:04.796Z