English

Resonant Inelastic X-ray Scattering Study of Ca$_3$Ru$_2$O$_7$

Strongly Correlated Electrons 2025-04-01 v2

Abstract

We present a combined oxygen KK-edge x-ray absorption spectroscopy (XAS) and resonant inelastic x-ray scattering (RIXS) study of the bilayer ruthenate Ca3_3Ru2_2O7_7. Our RIXS experiments on Ca3_3Ru2_2O7_7 were carried out on the overlapping planar and inter-planar oxygen resonances, which are distinguishable from the apical one. Comparison to equivalent oxygen KK-edge spectra recorded on band-Mott insulating Ca2_2RuO4_4 is made. In contrast to Ca2_2RuO4_4 spectra, which contain excitations linked to Mott physics, Ca3_3Ru2_2O7_7 spectra feature only intra-t2gt_{2g} ones that do not directly involve the Coulomb energy scale. As found in Ca2_2RuO4_4, we resolve two intra-t2gt_{2g} excitations in Ca3_3Ru2_2O7_7. Moreover, the lowest lying excitation in Ca3_3Ru2_2O7_7 shows a significant dispersion, revealing a collective character differently from what is observed in Ca2_2RuO4_4. Theoretical modelling supports the interpretation of this lowest energy excitation in Ca3_3Ru2_2O7_7 as a magnetic transverse mode with multi-particle character, whereas the corresponding excitation in Ca2_2RuO4_4 is assigned to combined longitudinal and transverse spin modes. These fundamental differences are discussed in terms of the inequivalent magnetic ground-state manifestations in Ca2_2RuO4_4 and Ca3_3Ru2_2O7_7.

Keywords

Cite

@article{arxiv.2004.13391,
  title  = {Resonant Inelastic X-ray Scattering Study of Ca$_3$Ru$_2$O$_7$},
  author = {K. von Arx and F. Forte and M. Horio and V. Granata and Q. Wang and L. Das and Y. Sassa and R. Fittipaldi and C. G. Fatuzzo and O. Ivashko and Y. Tseng and E. Paris and A. Vecchione and T. Schmitt and M. Cuoco and J. Chang},
  journal= {arXiv preprint arXiv:2004.13391},
  year   = {2025}
}

Comments

11 pages, 6 figures. This manuscript has been submitted to PRB