English

Renormalization of Hard-Core Guest Charges Immersed in Two-Dimensional Electrolyte

Statistical Mechanics 2009-11-11 v1

Abstract

This paper is a continuation of a previous one [L. {\v{S}}amaj, {\it J. Stat. Phys.} {\bf 120}:125 (2005)] dealing with the renormalization of a guest charge immersed in a two-dimensional logarithmic Coulomb gas of pointlike ±\pm unit charges, the latter system being in the stability-against-collapse regime of reduced inverse temperatures 0β<20\le \beta <2. In the previous work, using a sine-Gordon representation of the Coulomb gas, an exact renormalized-charge formula was derived for the special case of the {\em pointlike} guest charge QQ, in its stability regime βQ<2\beta | Q| < 2. In the present paper, we extend the renormalized-charge treatment to the guest charge with a hard core of radius σ\sigma, which allows us to go beyond the stability border βQ=2\beta| Q| = 2. In the limit of the hard-core radius much smaller than the correlation length of the Coulomb-gas species and at a strictly finite temperature, due to the counterion condensation in the extended region βQ>2\beta| Q| >2, the renormalized charge QrenQ_{\rm ren} turns out to be a periodic function of the bare charge QQ with period 1. The renormalized charge therefore does not saturate at a specific finite value as Q| Q| \to\infty, but oscillates between two extreme values. In the high-temperature Poisson-Boltzmann scaling regime of limits β0\beta\to 0 and QQ\to\infty with the product βQ\beta Q being finite, one reproduces correctly the monotonic dependence of βQren\beta Q_{\rm ren} on βQ\beta Q in the guest-charge stability region βQ<2\beta| Q| <2 and the Manning-Oosawa type of counterion condensation with the uniform saturation of βQren\beta Q_{\rm ren} at the value 4/π4/\pi in the region βQ2\beta| Q|\ge 2.

Keywords

Cite

@article{arxiv.cond-mat/0601692,
  title  = {Renormalization of Hard-Core Guest Charges Immersed in Two-Dimensional Electrolyte},
  author = {L. Samaj},
  journal= {arXiv preprint arXiv:cond-mat/0601692},
  year   = {2009}
}

Comments

28 pages, 1 figure