Renormalization of Hard-Core Guest Charges Immersed in Two-Dimensional Electrolyte
Abstract
This paper is a continuation of a previous one [L. {\v{S}}amaj, {\it J. Stat. Phys.} {\bf 120}:125 (2005)] dealing with the renormalization of a guest charge immersed in a two-dimensional logarithmic Coulomb gas of pointlike unit charges, the latter system being in the stability-against-collapse regime of reduced inverse temperatures . In the previous work, using a sine-Gordon representation of the Coulomb gas, an exact renormalized-charge formula was derived for the special case of the {\em pointlike} guest charge , in its stability regime . In the present paper, we extend the renormalized-charge treatment to the guest charge with a hard core of radius , which allows us to go beyond the stability border . In the limit of the hard-core radius much smaller than the correlation length of the Coulomb-gas species and at a strictly finite temperature, due to the counterion condensation in the extended region , the renormalized charge turns out to be a periodic function of the bare charge with period 1. The renormalized charge therefore does not saturate at a specific finite value as , but oscillates between two extreme values. In the high-temperature Poisson-Boltzmann scaling regime of limits and with the product being finite, one reproduces correctly the monotonic dependence of on in the guest-charge stability region and the Manning-Oosawa type of counterion condensation with the uniform saturation of at the value in the region .
Keywords
Cite
@article{arxiv.cond-mat/0601692,
title = {Renormalization of Hard-Core Guest Charges Immersed in Two-Dimensional Electrolyte},
author = {L. Samaj},
journal= {arXiv preprint arXiv:cond-mat/0601692},
year = {2009}
}
Comments
28 pages, 1 figure