English

Relativistically extended Blanchard recurrence relation for hydrogenic matrix elements

Atomic Physics 2016-08-16 v1

Abstract

General recurrence relations for arbitrary non-diagonal, radial hydrogenic matrix elements are derived in Dirac relativistic quantum mechanics. Our approach is based on a generalization of the second hypervirial method previously employed in the non-relativistic Schr\"odinger case. A relativistic version of the Pasternack-Sternheimer relation is thence obtained in the diagonal (i.e. total angular momentum and parity the same) case, from such relation an expression for the relativistic virial theorem is deduced. To contribute to the utility of the relations, explicit expressions for the radial matrix elements of functions of the form rλr^\lambda and βrλ\beta r^\lambda ---where β\beta is a Dirac matrix--- are presented.

Keywords

Cite

@article{arxiv.physics/0102017,
  title  = {Relativistically extended Blanchard recurrence relation for hydrogenic matrix elements},
  author = {R. P. Martínez-y-Romero and H. N. Núñez-Yépez and A. L. Salas-Brito},
  journal= {arXiv preprint arXiv:physics/0102017},
  year   = {2016}
}

Comments

21 pages, to be published in J. Phys. B: At. Mol. Opt. Phys. in April