Recommended Second Virial Coefficients for Nitrogen and Oxygen

We provide recommended values for the second virial coefficient, $B(T)$, and its uncertainty, for molecular nitrogen and oxygen. The temperature range covered is $20-3000$ K for nitrogen and $20-2000$ K for oxygen. The recommendations are based on tuning previously published state-of-the-art ab initio pair potentials so that the $B(T)$ calculated from the potentials match selected high-accuracy experimental data; for nitrogen the tuning utilizes values of $B$ derived from literature density data with greatly reduced uncertainty by analyzing the data with the aid of ab initio calculated higher virial coefficients. Quantum effects on $B$ are fully included with the path-integral Monte Carlo method. The resulting $B(T)$ have uncertainties similar to those of the best experimental data, but cover a much wider temperature range.