English

Rayleigh-Brillouin light scattering spectroscopy of nitrous oxide (N$_2$O)

Fluid Dynamics 2018-03-14 v1 Chemical Physics

Abstract

High signal-to-noise and high-resolution light scattering spectra are measured for nitrous oxide (N2_2O) gas at an incident wavelength of 403.00 nm, at 90^\circ scattering, at room temperature and at gas pressures in the range 0.540.5-4 bar. The resulting Rayleigh-Brillouin light scattering spectra are compared to a number of models describing in an approximate manner the collisional dynamics and energy transfer in this gaseous medium of this polyatomic molecular species. The Tenti-S6 model, based on macroscopic gas transport coefficients, reproduces the scattering profiles in the entire pressure range at less than 2\% deviation at a similar level as does the alternative kinetic Grad's 6-moment model, which is based on the internal collisional relaxation as a decisive parameter. A hydrodynamic model fails to reproduce experimental spectra for the low pressures of 0.5-1 bar, but yields very good agreement (<1< 1\%) in the pressure range 242-4 bar. While these three models have a different physical basis the internal molecular relaxation derived can for all three be described in terms of a bulk viscosity of ηb(6±2)×105\eta_b \sim (6 \pm 2) \times 10^{-5} Pa\cdots. A 'rough-sphere' model, previously shown to be effective to describe light scattering in SF6_6 gas, is not found to be suitable, likely in view of the non-sphericity and asymmetry of the N-N-O structured linear polyatomic molecule.

Keywords

Cite

@article{arxiv.1710.11193,
  title  = {Rayleigh-Brillouin light scattering spectroscopy of nitrous oxide (N$_2$O)},
  author = {Y. Wang and K. Liang and W. van de Water and W. Marques and W. Ubachs},
  journal= {arXiv preprint arXiv:1710.11193},
  year   = {2018}
}