Rayleigh-Brillouin light scattering spectroscopy of nitrous oxide (N$_2$O)
Abstract
High signal-to-noise and high-resolution light scattering spectra are measured for nitrous oxide (NO) gas at an incident wavelength of 403.00 nm, at 90 scattering, at room temperature and at gas pressures in the range bar. The resulting Rayleigh-Brillouin light scattering spectra are compared to a number of models describing in an approximate manner the collisional dynamics and energy transfer in this gaseous medium of this polyatomic molecular species. The Tenti-S6 model, based on macroscopic gas transport coefficients, reproduces the scattering profiles in the entire pressure range at less than 2\% deviation at a similar level as does the alternative kinetic Grad's 6-moment model, which is based on the internal collisional relaxation as a decisive parameter. A hydrodynamic model fails to reproduce experimental spectra for the low pressures of 0.5-1 bar, but yields very good agreement (\%) in the pressure range bar. While these three models have a different physical basis the internal molecular relaxation derived can for all three be described in terms of a bulk viscosity of Pas. A 'rough-sphere' model, previously shown to be effective to describe light scattering in SF gas, is not found to be suitable, likely in view of the non-sphericity and asymmetry of the N-N-O structured linear polyatomic molecule.
Keywords
Cite
@article{arxiv.1710.11193,
title = {Rayleigh-Brillouin light scattering spectroscopy of nitrous oxide (N$_2$O)},
author = {Y. Wang and K. Liang and W. van de Water and W. Marques and W. Ubachs},
journal= {arXiv preprint arXiv:1710.11193},
year = {2018}
}