Rate calculation with correlated noise
Chaotic Dynamics
2016-09-12 v2 Chemical Physics
Abstract
The usual identification of reactive trajectories for the calculation of reaction rates requires very time-consuming simulations, particularly if the environment presents memory effects. In this paper, we develop a new method that permits the identification of reactive trajectories in a system under the action of a stochastic colored driving. This method is based on the perturbative computation of the invariant structures that act as separatrices for reactivity. Furthermore, using this perturbative scheme, we have obtained a formally exact expression for the reaction rate in multidimensional systems coupled to colored noisy environments.
Keywords
Cite
@article{arxiv.1608.05397,
title = {Rate calculation with correlated noise},
author = {Thomas Bartsch and F. Revuelta and R. M. Benito and F. Borondo},
journal= {arXiv preprint arXiv:1608.05397},
year = {2016}
}
Comments
14 pages, 5 figures