English

Rate calculation with correlated noise

Chaotic Dynamics 2016-09-12 v2 Chemical Physics

Abstract

The usual identification of reactive trajectories for the calculation of reaction rates requires very time-consuming simulations, particularly if the environment presents memory effects. In this paper, we develop a new method that permits the identification of reactive trajectories in a system under the action of a stochastic colored driving. This method is based on the perturbative computation of the invariant structures that act as separatrices for reactivity. Furthermore, using this perturbative scheme, we have obtained a formally exact expression for the reaction rate in multidimensional systems coupled to colored noisy environments.

Keywords

Cite

@article{arxiv.1608.05397,
  title  = {Rate calculation with correlated noise},
  author = {Thomas Bartsch and F. Revuelta and R. M. Benito and F. Borondo},
  journal= {arXiv preprint arXiv:1608.05397},
  year   = {2016}
}

Comments

14 pages, 5 figures

R2 v1 2026-06-22T15:23:42.104Z