English

Quasiperiodic Frank-Kasper phases derived from the square-triangle dodecagonal tiling

Chemical Physics 2016-09-07 v1

Abstract

Frank-Kasper (F-K) phases form an important set of large-cell crystalline structures describing many inter-metallic alloys. They are usually described in term of their atomic environments, with atoms having 12,14,1512, 14, 15 and 1616 neighbours, coded into the canonical ZpZ_p cells (with pp the coordination number), the case p=12p=12 corresponding to a local icosahedral environment. In addition, the long range structure is captured by the geometry of a network (called either "major skeleton" or "disclination network") connecting only the non-icosahedral sites (with p12p\ne 12). Another interesting description, valid for the so-called "layered F-K phases", amounts to give simple rules to decorate specific periodic 2d tilings made of triangles and squares and eventually get the 3d periodic F-K phases. Quasicrystalline phases can sometime be found in the vicinity, in the phase diagram, of the F-K crystalline alloys; it is therefore of interest to understand if and how the standard F-K construction rules can be generalized on top of an underlying quasiperiodic structure. It is in particular natural to investigate how well square-triangle quasiperiodic tilings with dodecagonal symmetry, made of square and (equilateral) triangles, can be used as building frames to generate some F-K-like quasicrystalline structures. We show here how to produce two types of such structures, which are quasiperiodic in a plane and periodic in the third direction, and containing (or not) Z16Z_{16} sites.

Keywords

Cite

@article{arxiv.1609.01624,
  title  = {Quasiperiodic Frank-Kasper phases derived from the square-triangle dodecagonal tiling},
  author = {Jean-François Sadoc and Rémy Mosseri},
  journal= {arXiv preprint arXiv:1609.01624},
  year   = {2016}
}
R2 v1 2026-06-22T15:41:27.088Z