We successfully synthesized (p-Py-V)[Cu(hfac)2], a verdazyl-based complex. Molecular orbital calculations revealed five types of intermolecular interactions between the radical spins and two types of intramolecular interactions between the radical and the Cu spins, resulting in a spin-1/2 distorted honeycomb-based lattice. Additionally, competing ferromagnetic and antiferromagnetic (AF) interactions induce frustration. The magnetization curve displayed a multistage increase, including a zero-field energy gap. Considering the stronger AF interactions that form dimers and tetramers, the magnetic susceptibility and magnetization curves were qualitatively explained. These findings demonstrated that the quantum state, based on the dominant AF interactions, was stabilized due to the effects of frustration in the lattice. Hence, the exchange interactions forming two-dimensional couplings decoupled, reducing energy loss caused by frustration and leading to frustration-induced dimensional reduction.
@article{arxiv.2310.14569,
title = {Quantum gapped state in a spin-1/2 distorted honeycomb-based lattice with frustration},
author = {Hironori Yamaguchi and Satoshi Morota and Takanori Kida and Seiya Shimono and Koji Araki and Yoshiki Iwasaki and Yuko Hosokoshi and Masayuki Hagiwara},
journal= {arXiv preprint arXiv:2310.14569},
year = {2023}
}