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QED effects on the nuclear magnetic shielding of $^3$He

Atomic Physics 2022-01-05 v1 Chemical Physics

Abstract

The leading quantum electrodynamic corrections to the nuclear magnetic shielding in one- and two-electron atomic systems are obtained in a complete form, and the shielding constants of 1^1H, 3^3He+^+, and 3^3He are calculated to be 17.735436(3)10617.735\,436(3) \cdot 10^{-6}, 35.507434(9)10635.507\,434(9)\cdot 10^{-6}, and 59.967029(23)10659.967\,029(23)\cdot 10^{-6}, respectively. These results are orders of magnitude more accurate than previous ones, and, with the ongoing measurement of the nuclear magnetic moment of 3^3He+^+ and planned 3^3He2+^{2+}, they open the window for high-precision absolute magnetometry using 3^3He NMR probes. The presented theoretical approach is applicable to all other light atomic and molecular systems, which facilitates the improved determination of magnetic moments of any light nuclei.

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Cite

@article{arxiv.2111.12496,
  title  = {QED effects on the nuclear magnetic shielding of $^3$He},
  author = {Dominik Wehrli and Anna Spyszkiewicz-Kaczmarek and Mariusz Puchalski and Krzysztof Pachucki},
  journal= {arXiv preprint arXiv:2111.12496},
  year   = {2022}
}

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6 pages