English

Pulling and Stretching a Molecular Wire to Tune its Conductance

Mesoscale and Nanoscale Physics 2015-08-06 v2

Abstract

A scanning tunnelling microscope is used to pull a polythiophene wire from a Au(111) surface while measuring the current traversing the junction. Abrupt current increases measured during the lifting procedure are associated to the detachment of molecular sub-units, in apparent contradiction with the expected exponential decrease of the conductance with wire length. \textit{Ab initio} simulations reproduce the experimental data and demonstrate that this unexpected behavior is due to release of mechanical stress in the wire, paving the way to mechanically gated single-molecule electronic devices.

Keywords

Cite

@article{arxiv.1506.05653,
  title  = {Pulling and Stretching a Molecular Wire to Tune its Conductance},
  author = {Gaël Reecht and Hervé Bulou and Fabrice Scheurer and Virginie Speisser and Fabrice Mathevet and César González and Yannick J. Dappe and Guillaume Schull},
  journal= {arXiv preprint arXiv:1506.05653},
  year   = {2015}
}
R2 v1 2026-06-22T09:55:54.552Z