English

Pressure-induced Structural Phase Transition, Metallization, and Superconductivity in layered metalloid dichalcogenide 1T-SiTe$_2$

Superconductivity 2026-07-08 v1

Abstract

Layered transition-metal dichalcogenides (TMDs) have attracted considerable attention as promising platforms for exploring emergent physics and potential device applications. In contrast, metalloid-based dichalcogenide counterparts remain largely underexplored. Here, we report the pressure-induced structural phase transition, metallization, and superconductivity in the layered metalloid dichalcogenide 1T-SiTe2_2. At ambient pressure, 1T-SiTe2_2 crystallizes in a trigonal crystal structure (space group: P3ˉm1P\bar{3}m1) and exhibits intrinsic semiconducting transport characteristics. Upon pressurization, in concomitant with the suppression of semiconducting behavior in resistance, superconductivity emerges at around 6.7 GPa. The superconducting transition temperature (Tc_c) rises continuously with increasing pressure and finally saturates at approximately 5.5 K for pressures above 30 GPa. During the compression, 1T-SiTe2_2 experiences three structural phase transitions, and the phase transition pressures are highly consistent with the anomalous transport responses observed experimentally, indicating that the changes of transport behavior of 1T-SiTe2_2 under pressure are structurally-driven. Our work extends TMD superconductors into the realm of metalloid systems and provides a new platform for exploring novel physics in quasi two-dimensional materials without transition-metal elements.

Keywords

Cite

@article{arxiv.2607.07569,
  title  = {Pressure-induced Structural Phase Transition, Metallization, and Superconductivity in layered metalloid dichalcogenide 1T-SiTe$_2$},
  author = {Ying-Jie Zhang and Heng Xu and Zhe-Ning Xiang and Zong-Hui Wu and Qing Li and Hai-Hu Wen},
  journal= {arXiv preprint arXiv:2607.07569},
  year   = {2026}
}

Comments

26 pages total; 21 pages of main text with 5 figures, 5 pages of SI with 7 figures