Premelting of Thin Wires

Recent work has raised considerable interest on the nature of thin metallic wires. We have investigated the melting behavior of thin cylindrical Pb wires with the axis along a (110) direction, using molecular dynamics and a well-tested many-body potential. We find that---in analogy with cluster melting---the melting temperature $T_m (R)$ of a wire with radius $R$ is lower than that of a bulk solid, $T_m^b$, by $T_m (R) = T_m^b -c/R$. Surface melting effects, with formation of a thin skin of highly diffusive atoms at the wire surface, is observed. The diffusivity is lower where the wire surface has a flat, local (111) orientation, and higher at (110) and (100) rounded areas. The possible relevance to recent results on non-rupturing thin necks between an STM tip and a warm surface is addressed.