Research on charge-density-wave (CDW) ordered transition-metal dichalcogenides continues to unravel new states of quantum matter correlated to the intertwined lattice and electronic degrees of freedom. Here, we report an inelastic x-ray scattering investigation of the lattice dynamics of the canonical CDW compound 2H-TaSe2 complemented by angle-resolved photoemission spectroscopy. Our results rule out the central-peak scenario for the CDW transition in 2H-TaSe2 and provide evidence for a novel precursor phase above the CDW transition temperature TCDW. The phase at temperatures between T∗(=128.7,K) and TCDW(=121.3K) is characterized by a fully softened phonon mode and medium-range ordered (ξcorr=100A˚−200A˚) static CDW domains. Only TCDW is detectable in our photoemission experiments. Thus, 2H-TaSe2 exhibits structural before electronic static order and emphasizes the important lattice contribution to CDW transitions.
@article{arxiv.2207.11298,
title = {Precursor phase with full phonon softening above the charge-density-wave phase transition in $2H$-TaSe$_2$},
author = {Xingchen Shen and Rolf Heid and Roland Hott and Björn Salzmann and Marli dos Reis Cantarino and Claude Monney and Ayman H. Said and Bridget Murphy and Kai Rossnagel and Stephan Rosenkranz and Frank Weber},
journal= {arXiv preprint arXiv:2207.11298},
year = {2023}
}