English

Preconditioning for a Cahn-Hilliard-Navier-Stokes model for morphology formation in organic solar cells

Numerical Analysis 2026-01-26 v1 Numerical Analysis

Abstract

We present a model for the morphology evolution of printed organic solar cells which occurs during the drying of a mixture of polymer, the non-fullerene acceptor and the solvent. Our model uses a phase field approach coupled to a Navier-Stokes equation describing the macroscopic movement of the fluid. Additionally, we incorporate the evaporation process of the solvent using an Allen-Cahn equation. The model is discretized using a finite-element approach with a semi-implicit discretization in time. The resulting (non)linear systems are coupled and of large dimensionality. We present a preconditioned iterative scheme to solve them robustly with respect to changes in the discretization parameters. We illustrate that the preconditioned solver shows parameter-robust iteration numbers and that the model qualitatively captures the behavior of the film morphology during drying.

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Cite

@article{arxiv.2501.11767,
  title  = {Preconditioning for a Cahn-Hilliard-Navier-Stokes model for morphology formation in organic solar cells},
  author = {Pelin Çiloğlu and Carmen Tretmans and Roland Herzog and Jan-F. Pietschmann and Martin Stoll},
  journal= {arXiv preprint arXiv:2501.11767},
  year   = {2026}
}

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33 pages