English

Precision calculation of the bound-electron $g$ factor in molecular hydrogen ions

Atomic Physics 2025-08-07 v1

Abstract

We calculate the bound-electron gg factor for a wide range of rovibrational states of the molecular hydrogen ions H2+_2^+ and HD+^+. Relativistic and QED corrections of orders up to α5\alpha^5 are taken into account. All contributions are calculated in a nonrelativistic QED framework, except for relativistic corrections of order (Zα)4(Z\alpha)^4 and above, which are obtained by calculating the relativistic gg factor using a precise minmax finite element solution of the two-center Dirac equation. A relative accuracy of 45×10114-5 \times 10^{-11} is achieved for the scalar gg factor component, which represents an improvement by more than three orders of magnitude over previous calculations. These results are useful for internal state identification and rovibraional spectroscopy of single molecular hydrogen ions in Penning traps, and open a new avenue towards precision tests of QED.

Keywords

Cite

@article{arxiv.2508.04242,
  title  = {Precision calculation of the bound-electron $g$ factor in molecular hydrogen ions},
  author = {Ossama Kullie and Hugo D. Nogueira and Jean-Philippe Karr},
  journal= {arXiv preprint arXiv:2508.04242},
  year   = {2025}
}