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Possible EIT-like effects in strong-field photodissociation of carbon disulphide

Atomic Physics 2007-05-23 v1 Chemical Physics

Abstract

CS2_2 molecules are spatially aligned upon irradiation by intense (1-100 TW cm2^{-2}), 35 ps pulses of 512 nm or 355 nm light. When both colours are simultaneously present, spatial alignment disappears. We draw analogy with weak-field illumination of an atom by two colours wherein EIT (electromagnetically induced transparency) inhibits absorption by virtue of dipoles not being induced in two-colour fields. In the strong field scenario, molecular alignment is a consequence of a dipole being induced in the direction of the applied electric field. It follows, therefore, that when dipoles are not induced, no spatial alignment is to be expected.

Keywords

Cite

@article{arxiv.physics/0702227,
  title  = {Possible EIT-like effects in strong-field photodissociation of carbon disulphide},
  author = {F. A. Rajgara and D. Mathur and Hema Ramachandran},
  journal= {arXiv preprint arXiv:physics/0702227},
  year   = {2007}
}

Comments

To appear in Chemical Physics Letters