English

Polymers grafted to porous membranes

Soft Condensed Matter 2015-06-25 v1 Statistical Mechanics

Abstract

We study a single flexible chain molecule grafted to a membrane which has pores of size slightly larger than the monomer size. On both sides of the membrane there is the same solvent. When this solvent is good, i.e. when the polymer is described by a self avoiding walk, it can fairly easily penetrate the membrane, so that the average number of membrane crossings tends, for chain length NN\to\infty, to a positive constant. The average numbers of monomers on either side of the membrane diverges in this limit, although their ratio becomes infinite. For a poor solvent, in contrast, the entire polymer is located, for large NN, on one side of the membrane. For good and for theta solvents (ideal polymers) we find scaling laws, whose exponents can in the latter case be easily understood from the behaviour of random walks.

Keywords

Cite

@article{arxiv.cond-mat/0608464,
  title  = {Polymers grafted to porous membranes},
  author = {Hsiao-Ping Hsu and Peter Grassberger},
  journal= {arXiv preprint arXiv:cond-mat/0608464},
  year   = {2015}
}

Comments

4 pages, 6 figures