English

Pivotal condensation and chemical balancing

Rings and Algebras 2023-05-25 v2 Chemical Physics

Abstract

I present a universal method, called pivotal condensation, for calculating stoichiometric factors of chemical reactions. It can be done by hand, even for rather complicated reactions. The main trick, which I call kernel pivotal condensation (ker pc), to calculate the kernel of a matrix might be of independent interest. The discussion is elaborated for matrices with entries in a principal ideal domain RR. The ker pc calculates a basis with coefficients in RR for the kernel of a matrix, seen as e QQ-vector space, where QQ is the quotient field of RR. If WW is a free saturated RR-submodule of RnR^n I address the question how to modify an RR-basis of the QQ-vector subspace QRWQ\otimes _R W over the quotient field QQ to obtain a basis of the RR-module WW. I also indicate how one can solve inhomogeneous linear systems, invert matrices and determine the four subspaces using pivotal condensation. I formulate the balancing by inspection method that is widely used to reduce the size of a linear system arising in chemical balancing in mathematical language.

Keywords

Cite

@article{arxiv.2305.13313,
  title  = {Pivotal condensation and chemical balancing},
  author = {Hans-Christian Herbig},
  journal= {arXiv preprint arXiv:2305.13313},
  year   = {2023}
}

Comments

This is version 2. Minor errors have been corrected