Pivotal condensation and chemical balancing
Abstract
I present a universal method, called pivotal condensation, for calculating stoichiometric factors of chemical reactions. It can be done by hand, even for rather complicated reactions. The main trick, which I call kernel pivotal condensation (ker pc), to calculate the kernel of a matrix might be of independent interest. The discussion is elaborated for matrices with entries in a principal ideal domain . The ker pc calculates a basis with coefficients in for the kernel of a matrix, seen as e -vector space, where is the quotient field of . If is a free saturated -submodule of I address the question how to modify an -basis of the -vector subspace over the quotient field to obtain a basis of the -module . I also indicate how one can solve inhomogeneous linear systems, invert matrices and determine the four subspaces using pivotal condensation. I formulate the balancing by inspection method that is widely used to reduce the size of a linear system arising in chemical balancing in mathematical language.
Keywords
Cite
@article{arxiv.2305.13313,
title = {Pivotal condensation and chemical balancing},
author = {Hans-Christian Herbig},
journal= {arXiv preprint arXiv:2305.13313},
year = {2023}
}
Comments
This is version 2. Minor errors have been corrected