KxFe2−ySe2 exhibits an iron-vacancy ordering at Ts∼270degC and separates into two phases: a minor superconducting (iron-vacancy-disordered) phase and a major non-superconducting (iron-vacancy-ordered) phase. The microstructural and superconducting properties of this intermixture can be tuned by an appropriate control of the quenching process through Ts. A faster quenching rate leads to a finer microstructure and a suppression of formation of the non-superconducting phase by up to 50%. Nevertheless, such a faster cooling rate does induce a monotonic reduction in the superconducting transition temperature (from 30.7 K down to 26.0 K) and, simultaneously, a decrease in the iron content within the superconducting phase such that the compositional ratio changed from K0.35Fe1.83Se2 to K0.58Fe1.71Se2.
@article{arxiv.1701.04911,
title = {Phase-separation control of K$_x$Fe$_{2-y}$Se$_2$ superconductor through rapid-quenching process},
author = {Yusuke Yanagisawa and Masashi Tanaka and Aichi Yamashita and Kouji Suzuki and Hiroshi Hara and Mohammed ElMassalami and Hiroyuki Takeya and Yoshihiko Takano},
journal= {arXiv preprint arXiv:1701.04911},
year = {2017}
}