English

Orientation selection in lamellar phases by oscillatory shears

Soft Condensed Matter 2009-11-11 v1

Abstract

In order to address the selection mechanism that is responsible for the unique lamellar orientation observed in block copolymers under oscillatory shears, we use a constitutive law for the dissipative part of the stress tensor that respects the uniaxial symmetry of a lamellar phase. An interface separating two domains oriented parallel and perpendicular to the shear is shown to be hydrodynamically unstable, a situation analogous to the thin layer instability of stratified fluids under shear. The resulting secondary flows break the degeneracy between parallel and perpendicular lamellar orientation, leading to a preferred perpendicular orientation in certain ranges of parameters of the polymer and of the shear.

Keywords

Cite

@article{arxiv.cond-mat/0601355,
  title  = {Orientation selection in lamellar phases by oscillatory shears},
  author = {Zhi-Feng Huang and Jorge Vinals},
  journal= {arXiv preprint arXiv:cond-mat/0601355},
  year   = {2009}
}

Comments

4 pages, 3 figures

R2 v1 2026-07-22T11:27:36.900Z