English

Optimized free energies from bidirectional single-molecule force spectroscopy

Statistical Mechanics 2008-05-07 v2

Abstract

An optimized method for estimating path-ensemble averages using data from processes driven in opposite directions is presented. Based on this estimator, bidirectional expressions for reconstructing free energies and potentials of mean force from single-molecule force spectroscopy - valid for biasing potentials of arbitrary stiffness - are developed. Numerical simulations on a model potential indicate that these methods perform better than unidirectional strategies.

Keywords

Cite

@article{arxiv.0802.0224,
  title  = {Optimized free energies from bidirectional single-molecule force spectroscopy},
  author = {David D. L. Minh and Artur B. Adib},
  journal= {arXiv preprint arXiv:0802.0224},
  year   = {2008}
}

Comments

4 pages, 2 figures

R2 v1 2026-06-21T10:08:53.342Z