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On The Low-Frequency Vibrational Modes of C$_{60}$

mtrl-th 2015-06-26 v1 atom-ph chem-ph Materials Science

Abstract

The vibrational spectrum of C60_{60} is compared to the spectrum of a classical isotropic elastic spherical shell. We show correlations between the low frequency modes of C60_{60} and those of the spherical shell. We find the spherical model gives the approximate frequency ordering for the low frequency modes. We estimate a Poisson ratio of σ0.30\sigma\approx 0.30 and a transverse speed of sound of vs1800v_s\approx 1800 m/s for the equivalent elastic shell. We also find that ω(M1)/ω(M0)=32\omega({\rm M_1})/\omega({\rm M_0})=\sqrt{3\over 2} for the shell modes M0{\rm M_0} and M1{\rm M_1}, independent of elastic constants. We find that this ratio compares favorably with an experimental value of 1.17.

Keywords

Cite

@article{arxiv.mtrl-th/9604002,
  title  = {On The Low-Frequency Vibrational Modes of C$_{60}$},
  author = {Dennis P. Clougherty and John P. Gorman},
  journal= {arXiv preprint arXiv:mtrl-th/9604002},
  year   = {2015}
}

Comments

11 pages, 3 figures in Postscript, uses REVTEX, to be published in Chem. Phys. Lett