English

On the formation/dissolution of equilibrium droplets

Mathematical Physics 2009-11-07 v1 Statistical Mechanics math.MP Probability Chemical Physics

Abstract

We consider liquid-vapor systems in finite volume VRdV\subset\R^d at parameter values corresponding to phase coexistence and study droplet formation due to a fixed excess δN\delta N of particles above the ambient gas density. We identify a dimensionless parameter Δ(δN)(d+1)/d/V\Delta\sim(\delta N)^{(d+1)/d}/V and a \textrm{universal} value \Deltac=\Deltac(d)\Deltac=\Deltac(d), and show that a droplet of the dense phase occurs whenever Δ>\Deltac\Delta>\Deltac, while, for Δ<\Deltac\Delta<\Deltac, the excess is entirely absorbed into the gaseous background. When the droplet first forms, it comprises a non-trivial, \textrm{universal} fraction of excess particles. Similar reasoning applies to generic two-phase systems at phase coexistence including solid/gas--where the ``droplet'' is crystalline--and polymorphic systems. A sketch of a rigorous proof for the 2D Ising lattice gas is presented; generalizations are discussed heuristically.

Keywords

Cite

@article{arxiv.math-ph/0207012,
  title  = {On the formation/dissolution of equilibrium droplets},
  author = {Marek Biskup and Lincoln Chayes and Roman Kotecky},
  journal= {arXiv preprint arXiv:math-ph/0207012},
  year   = {2009}
}

Comments

An announcement of a forthcoming rigorous work on the 2D Ising model; to appear in Europhys. Lett

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