English

On the electrostatic potential profile in biased molecular wires

Chemical Physics 2007-05-23 v1 Mesoscale and Nanoscale Physics

Abstract

The potential profile across a biased molecular junction is calculated within the framework of a simple Thomas-Fermi type screening model. In particular, the relationship between this profile and the lateral molecular cross section is examined. We find that a transition from a linear potential profile to a potential that drops mainly near the molecule-metal contacts occurs with increasing cross section width, in agreement with numerical quantum calculations.

Keywords

Cite

@article{arxiv.physics/0207124,
  title  = {On the electrostatic potential profile in biased molecular wires},
  author = {Abraham Nitzan and Michael Galperin and Gert-Ludwig Ingold and Hermann Grabert},
  journal= {arXiv preprint arXiv:physics/0207124},
  year   = {2007}
}

Comments

6 pages, 5 figures, RevTeX4

R2 v1 2026-07-22T18:54:00.863Z