On Maximal Total Entropy Production Models for Steady Evaporation of a Calorically Perfect Polyatomic Gas

This study investigates the boundary conditions for fluid-dynamic equations at the interface of a gas and its condensed phase during steady evaporation of a polyatomic gas. Evaporation curves illustrating the dependence of the temperature and pressure ratios on the Mach number are considered for a calorically perfect gas whose molecules behave like rigid rotors. At the condensed phase, complete absorption conditions are assumed. Also an extension to cases in which a part of the molecules is diffusely reflected at the condensed phase is also considered. We revisit the half-space evaporation problem for polyatomic gases based on previous results, applied to a slightly modified entropy functional. The structure of the (modified) maximal total entropy production curves is investigated, and simple functions that accurately fit the numerical results are proposed. Functions of the proposed form, with modified coefficients, also fit the evaporation curves previously obtained by different numerical methods surprisingly well. The approximation is performed for different numbers of internal degrees of freedom or ratios of specific heats. Simple functions that depend on the ratio of specific heats are found to fit the obtained evaporation curves for different ratios of specific heats very well.