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On a dual representation of the Goldstone manifold

Chemical Physics 2020-04-13 v1 Quantum Physics

Abstract

An intrinsic wavefunction with a broken continuous symmetry can be rotated with no energy penalty leading to an infinite set of degenerate states known as a Goldstone manifold. In this work, we show that a dual representation of such manifold exists that is sampled by an infinite set of non-degenerate states. A proof that both representations are equivalent is provided. From the work of Peierls and Yoccoz (Proc. Phys. Soc. A {\bf 70}, 381 (1957)), it is known that collective states with good symmetries can be obtained from the Goldstone manifold using a generator coordinate trial wavefunction. We show that an analogous generator coordinate can be used in the dual representation; we provide numerical evidence using an intrinsic wavefunction with particle number symmetry-breaking for the electronic structure of the Be atom and one with S^z\hat{S}^z symmetry-breaking for a H5_5 ring. We discuss how the dual representation can be used to evaluate expectation values of symmetry-projected states when the norm ΦP^qΦ|\langle \Phi | \hat{P}^q | \Phi \rangle| becomes very small.

Keywords

Cite

@article{arxiv.2004.05047,
  title  = {On a dual representation of the Goldstone manifold},
  author = {Carlos A. Jiménez-Hoyos and Rayner R. Rodríguez-Guzmán and Thomas M. Henderson and Gustavo E. Scuseria},
  journal= {arXiv preprint arXiv:2004.05047},
  year   = {2020}
}

Comments

8 pages, 7 figures