The charge transfer antiferromagnetic (TN =220 K) insulator EuNiO3 undergoes, at ambient pressure, a temperature-induced metal insulator MI transition at TMI=463 K. We have investigated the effect of pressure (up to p~20 GPa) on the electronic, magnetic and structural properties of EuNiO3 using electrical resistance measurements, {151}^Eu nuclear resonance scattering of synchrotron radiation and x-ray diffraction, respectively. With increasing pressure we find at pc =5.8 GPa a transition from the insulating state to a metallic state, while the orthorhombic structure remains unchanged up to 20 GPa. The results are explained in terms of a gradual increase of the electronic bandwidth with increasing pressure, which results in a closing of the charge transfer gap. It is further shown that the pressure-induced metallic state exhibits magnetic order with a lowervalue of TN (TN ~120 K at 9.4 GPa) which disappears between 9.4 and 14.4 GPa.
@article{arxiv.cond-mat/0504285,
title = {Observation of insulator-metal transition in EuNiO$_{3}$ under high pressure},
author = {R. Lengsdorf and A. Barla and J. A. Alonso and M. J. Martinez-Lope and H. Micklitz and M. M. Abd-Elmeguid},
journal= {arXiv preprint arXiv:cond-mat/0504285},
year = {2009}
}