English

Observation and laser spectroscopy of ytterbium monomethoxide, YbOCH$_3$

Atomic Physics 2021-02-24 v1 Chemical Physics

Abstract

We describe a laser spectroscopic study of ytterbium monomethoxide, YbOCH3_3, a species of interest to searches for time-reversal symmetry violation using laser-cooled molecules. We report measurements of vibrational structure in the X~\tilde{X} and A~\tilde{A} states, vibrational branching ratios for several components of the A~\tilde{A} state, and radiative lifetimes of low-lying electronic states. Ab initio\textit{Ab initio} calculations are used to aid the assignment of vibronic emission bands and provide insight into the electronic and vibrational structure. Our results demonstrate that rapid optical cycling is feasible for YbOCH3_3, opening a path to orders-of-magnitude increased sensitivity in future measurements of P- and/or T-violating physics.

Keywords

Cite

@article{arxiv.2012.01212,
  title  = {Observation and laser spectroscopy of ytterbium monomethoxide, YbOCH$_3$},
  author = {Benjamin L. Augenbraun and Zack D. Lasner and Alexander Frenett and Hiromitsu Sawaoka and Anh T. Le and John M. Doyle and Timothy C. Steimle},
  journal= {arXiv preprint arXiv:2012.01212},
  year   = {2021}
}

Comments

14 pages, 5 figures