We show that in some transition metal dichalcogenides, minority regions of the cleaved sample surfaces show - unexpectedly and anomalously - a finite number of 2D electronic states instead of the expected 3D valence bands. In the case of NbS\textsubscript{2}, in addition to the typical spectrum associated with bulk 2Ha stacking, we also find minority regions with electronic structures consistent with few-layers of 3R stacking. In MoS\textsubscript{2} we find areas of both bulk 2Hc and 3R stackings, and regions exhibiting finite-layer quantisation of both types. We further find evidence for a more exotic 4Ha stacking of MoS\textsubscript{2}, in which the valence band maximum is quasi-2D. The results highlight how variation of the interlayer stacking of van der Waals materials beyond the commonly-reported bulk polytypes can yield novel electronic structures.
@article{arxiv.2406.19793,
title = {Novel electronic structures from anomalous stackings in NbS$_2$ and MoS$_2$},
author = {Matthew D. Watson and Mihir Date and Alex Louat and Niels B. M. Schröter},
journal= {arXiv preprint arXiv:2406.19793},
year = {2024}
}