The linear electronic dispersion relation of graphene endows the atomically thin carbon layer with a large intrinsic optical nonlinearity, with regard to both parametric and photothermal processes. While plasmons in graphene nanostructures can further enhance nonlinear optical phenomena, boosting resonances to the technologically relevant mid- and near-infrared (IR) spectral regime necessitates patterning on ∼10 nm length scales, for which quantum finite-size effects play a crucial role. Here we show that thermoplasmons in narrow graphene nanoribbons can be activated at mid- and near-IR frequencies with moderate absorbed energy density, and furthermore can drive substantial third-harmonic generation and optical Kerr nonlinearities. Our findings suggest that photothermal excitation by ultrashort optical pulses offers a promising approach to enable nonlinear plasmonic phenomena in nanostructured graphene that avoids potentially invasive electrical gating schemes and excessive charge carrier doping levels.
@article{arxiv.2408.14798,
title = {Nonlinear thermoplasmonics in graphene nanostructures},
author = {Line Jelver and Joel D. Cox},
journal= {arXiv preprint arXiv:2408.14798},
year = {2026}
}