English

Nonequilibrium molecular dynamics of complex fluids near the gel point

Soft Condensed Matter 2007-05-23 v1

Abstract

We have carried out nonequilibrium molecular dynamics simulations of a system of crosslinked particles under shear flow conditions. As the fraction of crosslinks pp is increased the system approaches a gel point at which the shear viscosity η\eta and the first and second normal stress coefficients Ψ1\Psi_1 and Ψ2\Psi_2 diverge. All three quantities seem to diverge with a power law form: ηϵs\eta\sim \epsilon^{-s}, Ψ1,2ϵλ\Psi_{1,2}\sim\epsilon^{-\lambda} where ϵ=pcp\epsilon =p_c-p and s0.7s\approx 0.7 and λ3.15\lambda\approx 3.15 in three dimensions and s2.0s\approx 2.0 and λ6.0\lambda\approx 6.0 in two dimensions.

Keywords

Cite

@article{arxiv.cond-mat/0506123,
  title  = {Nonequilibrium molecular dynamics of complex fluids near the gel point},
  author = {Daniel C. Vernon and Michael Plischke},
  journal= {arXiv preprint arXiv:cond-mat/0506123},
  year   = {2007}
}

Comments

5 pages, 9 figures