English

Non-additive Stochastic Model for Supercooled Liquids: New Perspectives for Glass Science

Statistical Mechanics 2024-04-02 v1

Abstract

We present a review of the Non-additive Stochastic Model for supercooled liquids (NSM), an efficient approach for diffusive processes that provides a suitable interpretation for the non-Arrhenius dynamics in these materials. Based on a class of non-homogeneous continuity equations, the NSM provides functions able to model the thermal behavior of the viscosity and diffusivity in fragile liquids. The model defines a rigorous physical criterion that distinguishes super-Arrhenius from sub-Arrhenius processes, establishes a robust scale of fragility, describes fragile-to-strong curves in Angell's plot, and provides an accurate fitting equation for experimental viscosity data as effective as other viscosity classic models.

Keywords

Cite

@article{arxiv.2404.00379,
  title  = {Non-additive Stochastic Model for Supercooled Liquids: New Perspectives for Glass Science},
  author = {Antonio Cesar do Prado Rosa Junior and Elias Brito Alves Junior and Wanisson Silva Santana and Clebson Cruz},
  journal= {arXiv preprint arXiv:2404.00379},
  year   = {2024}
}