In the context of topcolor-assisted techicolor(TC2) models, we study the contributions of the neutral top-pion πt0 to the lepton flavor violating(LFV) processes li→ljγ and li→ljlkll. We find that the present experimental bound on μ→eγ gives severe constraints on the free parameters of TC2 models. Taking into account these constraints, we consider the processes li→ljlkll generated by top-pion exchange at the tree-level and the one loop level, and obtain Br(μ→3e)≃2.87×10−14, 1.1×10−15≤Br(τ→3e)≃Br(τ→2eμ)≤4.4×10−15, 3.1×10−15≤Br(τ→2μe)≃Br(τ→3μ)≤1.5×10−14 in most of the parameter space.