English

Nature of Hydrogen Bond in Water

Chemical Physics 2012-02-27 v1

Abstract

The work is devoted to the investigation of physical nature of H-bond. The H-bond potential ΦH(r,Ω)\Phi_{H} (r,\Omega) is studied as an irreducible part of the interaction energy of water molecules. It is defined as a difference between generalized Stillinger-David potential and the sum of dispersive and multipole interaction potentials. Relative contribution of ΦH(r,Ω)\Phi_{H} (r,\Omega) to intermolecular potential does not exceed (10\div15)%.

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Cite

@article{arxiv.1202.3035,
  title  = {Nature of Hydrogen Bond in Water},
  author = {Paul Makhlaichuk and Mykola Malomuzh and Igor Zhyganiuk},
  journal= {arXiv preprint arXiv:1202.3035},
  year   = {2012}
}