English

MoOCl$_2$ as a Hyperbolic Planar Platform for Nanooptics at Telecom Frequencies

Optics 2026-02-11 v1

Abstract

On-chip optoelectronics is fundamental to modern telecommunication, yet the diffraction limit of light remains a major obstacle to the extreme miniaturization of photonic integrated circuits (PICs). Hyperbolic polaritons (HPs) - hybrid light-matter excitations in materials with opposite-signed dielectric permittivity tensor components - offer a solution through their ability to support deep sub-wavelength confinement and unique optical phenomena such as canalization and negative refraction. To date, however, the most widely studied hyperbolic van der Waals (vdW) crystals, including hBN and α\alpha-MoO3_3, operate mainly in the mid-infrared, leaving the telecommunication bands (1260-1675 nm) largely uncovered. Here, we predict HPs operating directly in the telecommunication window in the vdW crystal molybdenum oxychloride (MoOCl2_2). Building on recent evidence that MoOCl2_2 can support plasmon polaritons in the visible, we theoretically investigate its optical response at telecom wavelengths and identify the conditions under which strongly confined, canalized HPs modes emerge. Beyond establishing a telecom platform, we outline device-level opportunities enabled by these modes, including diffraction-free waveguides based on canalization, tunable polaritonic crystals, and high-efficiency spontaneous emission-enhancement platforms. These paradigms cover the essential pillars of on-chip information processing: emission, propagation, modulation and detection. Our results establish MoOCl2_2 as a potentially transformative material that bridges physics of hyperbolic PPs with potential practical implementations, opening avenues for ultra-compact, high-density, and low-power photonic components.

Keywords

Cite

@article{arxiv.2602.09186,
  title  = {MoOCl$_2$ as a Hyperbolic Planar Platform for Nanooptics at Telecom Frequencies},
  author = {Haozhe Tong and Clara Clemente-Marcuello and Kirill V. Voronin and Pablo Alonso-González and Alexey Y. Nikitin},
  journal= {arXiv preprint arXiv:2602.09186},
  year   = {2026}
}

Comments

14 pages, 4 figures