English

Molecular Nanomagnet $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ as Resource for Bipartite and Tripartite Quantum Entanglement and Coherence

Quantum Physics 2025-10-07 v2 Statistical Mechanics

Abstract

We investigate key quantum characteristics of the mixed spin-(1/2,1,1/2) Heisenberg trimer under the influence of an external magnetic field. Specifically, we analyze the distributions of bipartite and tripartite entanglement quantified through the respective negativities, and the l1l_1-norm of coherence with the help of rigorous analytical and numerical methods. Our findings suggest that the heterotrinuclear molecular nanomagnet [{CuIIL}2NiII(H2O)2](ClO4)2.3H2O[\{\text{Cu}^\text{II}\text{L}\}_2\text{Ni}^\text{II}(\text{H}_2\text{O})_2](\text{ClO}_4)_{2} . 3\text{H}_2\text{O}, which represents an experimental realization of the mixed spin-(1/2,1,1/2) Heisenberg trimer, exhibits a significant bipartite entanglement between CuII\text{Cu}^\text{II} and NiII\text{Ni}^\text{II} magnetic ions along with robust tripartite entanglement among all three constituent CuIINiIICuII\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II} magnetic ions. The significant bipartite and tripartite entanglement persists even at relatively high temperatures up to 37K37\,\text{K} and magnetic fields up to 46T46\,\text{T}, whereby the coherence is maintained even at elevated temperatures. {It is evidenced that the aforementioned molecular complex with the magnetic core CuIINiIICuII\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II} provides an intriguing quantum resource, which exhibits a star-shaped state within the singlet eigenstate at low magnetic fields and W-like state within the triplet eigenstate at moderate magnetic fields.

Keywords

Cite

@article{arxiv.2407.07037,
  title  = {Molecular Nanomagnet $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ as Resource for Bipartite and Tripartite Quantum Entanglement and Coherence},
  author = {Azadeh Ghannadan and Hamid Arian Zad and Saeed Haddadi and Jozef Strečka and Zhirayr Adamyan and Vadim Ohanyan},
  journal= {arXiv preprint arXiv:2407.07037},
  year   = {2025}
}

Comments

15 pages, 5 figures