English

Molecular-Brownian Correspondence in the Hard-sphere Dynamic Universality Class

Soft Condensed Matter 2013-09-04 v2

Abstract

We perform systematic simulation experiments on model systems with soft-sphere repulsive interactions to test the predicted dynamic equivalence between soft-sphere liquids with similar static structure. For this we compare the simulated dynamics (mean squared displacement, intermediate scattering function, {\alpha}-relaxation time, etc.) of different soft-sphere systems, between them and with the hard-sphere liquid. We then show that the referred dynamic equivalence does not depend on the (Newtonian or Brownian) nature of the microscopic laws of motion of the constituent particles, and hence, applies independently to colloidal and to atomic simple liquids. In addition, we verify another more recently-proposed dynamic equivalence, this time between the long-time dynamics of a Brownian fluid and its corresponding atomic liquid (i.e., the atomic system with the same interaction potential).

Keywords

Cite

@article{arxiv.1302.3286,
  title  = {Molecular-Brownian Correspondence in the Hard-sphere Dynamic Universality Class},
  author = {Leticia López-Flores and Honorina Ruiz-Estrada and Martín Chávez-Páez and Magdaleno Medina-Noyola},
  journal= {arXiv preprint arXiv:1302.3286},
  year   = {2013}
}

Comments

16 pages,19 figures

R2 v1 2026-06-21T23:25:52.451Z