Hexagonal boron nitride has already been proven to serve as a decent substrate for high quality epitaxial growth of several 2D materials, such as graphene, MoSe2, MoS2 or WSe2. Here, we present for the first time the molecular beam epitaxy growth of MoTe2 on atomically smooth hexagonal boron nitride (hBN) substrate. Occurrence of MoTe2 in various crystalline phases such as distorted octahedral 1T' phase with semimetal properties or hexagonal 2H phase with semiconducting properties opens a possibility of realisation of crystal-phase homostructures with tunable properties. Atomic force microscopy studies of MoTe2 grown in a single monolayer regime enable us to determine surface morphology as a function of the growth conditions. The diffusion constant of MoTe2 grown on hBN can be altered 5 times by annealing after the growth, reaching about 5 ⋅ 10−6 cm2/s. Raman spectroscopy results suggest a coexistence of both 2H and 1T' MoTe2 phases in the studied samples.
@article{arxiv.2111.12433,
title = {Molecular Beam Epitaxy growth of MoTe$_2$ on Hexagonal Boron Nitride},
author = {Bartłomiej Seredyński and Rafał Bożek and Jan Suffczyński and Justyna Piwowar and Janusz Sadowski and Wojciech Pacuski},
journal= {arXiv preprint arXiv:2111.12433},
year = {2023}
}