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Molecular Beam Epitaxy growth of MoTe$_2$ on Hexagonal Boron Nitride

Materials Science 2023-07-06 v4

Abstract

Hexagonal boron nitride has already been proven to serve as a decent substrate for high quality epitaxial growth of several 2D materials, such as graphene, MoSe2_{\tiny{\textrm{2}}}, MoS2_{\tiny{\textrm{2}}} or WSe2_{\tiny{\textrm{2}}}. Here, we present for the first time the molecular beam epitaxy growth of MoTe2_{\tiny{\textrm{2}}} on atomically smooth hexagonal boron nitride (hBN) substrate. Occurrence of MoTe2_{\tiny{\textrm{2}}} in various crystalline phases such as distorted octahedral 1T' phase with semimetal properties or hexagonal 2H phase with semiconducting properties opens a possibility of realisation of crystal-phase homostructures with tunable properties. Atomic force microscopy studies of MoTe2_{\tiny{\textrm{2}}} grown in a single monolayer regime enable us to determine surface morphology as a function of the growth conditions. The diffusion constant of MoTe2_{\tiny{\textrm{2}}} grown on hBN can be altered 5 times by annealing after the growth, reaching about 5 \cdot 106^{-6} cm2^{2}/s. Raman spectroscopy results suggest a coexistence of both 2H and 1T' MoTe2_{\tiny{\textrm{2}}} phases in the studied samples.

Keywords

Cite

@article{arxiv.2111.12433,
  title  = {Molecular Beam Epitaxy growth of MoTe$_2$ on Hexagonal Boron Nitride},
  author = {Bartłomiej Seredyński and Rafał Bożek and Jan Suffczyński and Justyna Piwowar and Janusz Sadowski and Wojciech Pacuski},
  journal= {arXiv preprint arXiv:2111.12433},
  year   = {2023}
}

Comments

8 pages, 4 figures