Modeling of Transient Absorption Spectra in Exciton Charge-Transfer Systems
Chemical Physics
2018-11-28 v1
Abstract
Time-resolved spectroscopy provides the main tool for analyzing the dynamics of excitonic energy transfer in light-harvesting complexes. To infer time-scales and effective coupling parameters from experimental data requires to develop numerical exact theoretical models. The finite duration of the laser-molecule interactions and the reorganization process during the exciton migration affect the location and strength of spectroscopic signals. We show that the non-perturbative hierarchical equations of motion (HEOM) method captures these processes in a model exciton system, including the charge transfer state.
Keywords
Cite
@article{arxiv.1811.10683,
title = {Modeling of Transient Absorption Spectra in Exciton Charge-Transfer Systems},
author = {Tobias Kramer and Mirta Rodriguez and Yaroslav Zelinskyy},
journal= {arXiv preprint arXiv:1811.10683},
year = {2018}
}