Microscopic theory for electrocaloric effects in planar double layer systems
Soft Condensed Matter
2015-04-01 v1 Mesoscale and Nanoscale Physics
Materials Science
Statistical Mechanics
Abstract
We present a field theory approach to study changes in local temperature due to an applied electric field (the electrocaloric effect) in electrolyte solutions. Steric effects and a field-dependent dielectric function are found to be of paramount importance for accurate estimations of the electrocaloric effect. Interestingly, electrolyte solutions are found to exhibit negative electrocaloric effects. Overall, our results point toward using fluids near room temperature with low heat capacity and high salt concentration for enhanced electrocalorics.
Cite
@article{arxiv.1503.09141,
title = {Microscopic theory for electrocaloric effects in planar double layer systems},
author = {Rajeev Kumar and Jyoti P. Mahalik and Evgheni Strelcov and Alexander Tselev and Bradley S. Lokitz and Sergei. V. Kalinin and Bobby G. Sumpter},
journal= {arXiv preprint arXiv:1503.09141},
year = {2015}
}
Comments
25 pages, 5 figures