English

Microscopic model for spreading of a two-dimensional monolayer

Soft Condensed Matter 2007-05-23 v1 Materials Science

Abstract

We study the behavior of a monolayer, which occupies initially a bounded region on an ideal crystalline surface and then evolves in time due to random hopping motion of the monolayer particles. In the case when the initially occupied region is the half-plane X0X \leq 0, we determine explicitly, in terms of an analytically solvable mean-field-type approximation, the mean displacement X(t)X(t) of the monolayer edge. We find that X(t)AD0tX(t) \approx A \sqrt{D_{0} t}, in which law D0D_{0} denotes the bare diffusion coefficient and the prefactor AA is a function of the temperature and of the particle-particle interactions parameters. We show that AA can be greater, equal or less than zero, and specify the critical parameter which distinguishes between the regimes of spreading (A>0)A > 0), partial wetting (A=0A = 0) and dewetting (A<0A < 0).

Keywords

Cite

@article{arxiv.cond-mat/9804271,
  title  = {Microscopic model for spreading of a two-dimensional monolayer},
  author = {G. Oshanin and J. De Coninck and A. M. Cazabat and M. Moreau},
  journal= {arXiv preprint arXiv:cond-mat/9804271},
  year   = {2007}
}

Comments

19 pages, 4 figures, to appear in J. of Mol. Liquids

R2 v1 2026-07-22T12:03:32.611Z