English

Microcanonical solution of the mean-field $\phi^4$ model: comparison with time averages at finite size

Statistical Mechanics 2009-11-11 v1

Abstract

We solve the mean-field ϕ4\phi^4 model in an external magnetic field in the microcanonical ensemble using two different methods. The first one is based on Rugh's microcanonical formalism and leads to express macroscopic observables, such as temperature, specific heat, magnetization and susceptibility, as time averages of convenient functions of the phase-space. The approach is applicable for any finite number of particles NN. The second method uses large deviation techniques and allows us to derive explicit expressions for microcanonical entropy and for macroscopic observables in the NN \to\infty limit. Assuming ergodicity, we evaluate time averages in molecular dynamics simulations and, using Rugh's approach, we determine the value of macroscopic observables at finite NN. These averages are affected by a slow time evolution, often observed in systems with long-range interactions. We then show how the finite NN time averages of macroscopic observables converge to their corresponding NN\to\infty values as NN is increased. As expected, finite size effects scale as N1N^{-1}.

Keywords

Cite

@article{arxiv.cond-mat/0509030,
  title  = {Microcanonical solution of the mean-field $\phi^4$ model: comparison with time averages at finite size},
  author = {Alessandro Campa and Stefano Ruffo},
  journal= {arXiv preprint arXiv:cond-mat/0509030},
  year   = {2009}
}

Comments

18 pages, 1 figure