English

Measuring subdiffusion parameters

Statistical Mechanics 2013-05-29 v4

Abstract

We propose a method to extract from experimental data the subdiffusion parameter α\alpha and subdiffusion coefficient DαD_\alpha which are defined by means of the relation <x2>=2Dα/Γ(1+α)tα<x^2> =2D_\alpha/\Gamma(1+\alpha) t^\alpha where <x2><x^2> denotes a mean square displacement of a random walker starting from x=0x=0 at the initial time t=0t=0. The method exploits a membrane system where a substance of interest is transported in a solvent from one vessel to another across a thin membrane which plays here only an auxiliary role. Using such a system, we experimentally study a diffusion of glucose and sucrose in a gel solvent. We find a fully analytic solution of the fractional subdiffusion equation with the initial and boundary conditions representing the system under study. Confronting the experimental data with the derived formulas, we show a subdiffusive character of the sugar transport in gel solvent. We precisely determine the parameter α\alpha, which is smaller than 1, and the subdiffusion coefficient DαD_\alpha.

Keywords

Cite

@article{arxiv.cond-mat/0309072,
  title  = {Measuring subdiffusion parameters},
  author = {T. Kosztolowicz and K. Dworecki and St. Mrowczynski},
  journal= {arXiv preprint arXiv:cond-mat/0309072},
  year   = {2013}
}

Comments

17 pages, 9 figures, revised, to appear in Phys. Rev. E