Matrix approach to generalized ensemble theory for nonequilibrium discrete systems
Abstract
A universal and rigorous ensemble framework for nonequilibrium system remains lacking. Here, we provide a concise framework for the generalized ensemble theory of nonequilibrium discrete systems using matrix-based approach. By introducing an observation matrix, we show that any discrete probability distribution can be formulated as a generalized Boltzmann distribution, with observables and their conjugate variables serving as basis vectors and coordinates in a vector space. Within this framework, we identify the minimal sufficient statistics required to infer the Boltzmann distribution. The nonequilibrium thermodynamic relations and fluctuation-dissipation relations naturally emerge from this framework. Our findings provide a new approach to developing generalized ensemble theory for nonequilibrium discrete systems.
Keywords
Cite
@article{arxiv.2503.17898,
title = {Matrix approach to generalized ensemble theory for nonequilibrium discrete systems},
author = {Shaohua Guan},
journal= {arXiv preprint arXiv:2503.17898},
year = {2025}
}
Comments
11 pages, 2 figures