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Magnetically Enhanced Thermoelectric Effect Driven by Martensitic Transformation in the Weak Itinerant Ferromagnet Co$_2$NbSn

Materials Science 2025-10-10 v1 Strongly Correlated Electrons

Abstract

We investigated the magnetic and thermoelectric properties of the full Heusler alloy Co2_2NbSn, which exhibits a martensitic transformation at 240 K. Magnetization measurements reveal weak itinerant ferromagnetism in the martensitic phase, which is well described by Takahashi's spin fluctuation theory. The characteristic spin fluctuation parameters were estimated to be T_0 = 1.0×\times10^3 K and T_A = 7.2×\times10^3 K. Seebeck coefficient measurements under magnetic fields up to 9 T show complex temperature and field dependence, which we decomposed into electron diffusion, spin fluctuation drag, and magnon drag components. A significant magnon-drag contribution was identified in both austenite and martensitic phases. Remarkably, this contribution is strongly enhanced in the martensitic phase compared to the austenite phase, despite a smaller magnetic moment. These findings provide evidence for robust low-energy spin excitations and highlight the potential of martensitic transformation in enhancing the thermoelectric performance of itinerant ferromagnetic alloys.

Keywords

Cite

@article{arxiv.2509.17378,
  title  = {Magnetically Enhanced Thermoelectric Effect Driven by Martensitic Transformation in the Weak Itinerant Ferromagnet Co$_2$NbSn},
  author = {Takumi Kihara and Xiao Xu and Yuki Ogi and Yoshiya Adachi and Tufan Roy and Ryuji Matsuura and Takeshi Kanomata},
  journal= {arXiv preprint arXiv:2509.17378},
  year   = {2025}
}

Comments

18 pages, 8 figures