English

Magnetic surface reconstruction in the van-der-Waals antiferromagnet Fe$_{1+x}$Te

Strongly Correlated Electrons 2021-01-22 v1 Materials Science Superconductivity

Abstract

Fe1+x_{1+x}Te is a two dimensional van der Waals antiferromagnet that becomes superconducting on anion substitution on the Te site. The parent phase of Fe1+x_{1+x}Te is sensitive to the amount of interstitial iron situated between the iron-tellurium layers displaying collinear magnetic order coexisting with low temperature metallic resistivity for small concentrations of interstitial iron xx and helical magnetic order for large values of xx. While this phase diagram has been established through scattering [see for example E. E. Rodriguez et al.\textit{et al.} Phys. Rev. B 84{\bf{84}}, 064403 (2011) and S. R\"ossler et al.\textit{et al.} Phys. Rev. B 84{\bf{84}}, 174506 (2011)], recent scanning tunnelling microscopy measurements [C. Trainer et al.\textit{et al.} Sci. Adv. 5{\bf{5}}, eaav3478 (2019)] have observed a different magnetic structure for small interstitial iron concentrations xx with a significant canting of the magnetic moments along the crystallographic cc axis of θ\theta=28 ±\pm 3^{\circ}. In this paper, we revisit the magnetic structure of Fe1.09_{1.09}Te using spherical neutron polarimetry and scanning tunnelling microscopy to search for this canting in the bulk phase and compare surface and bulk magnetism. The results show that the bulk magnetic structure of Fe1.09_{1.09}Te is consistent with collinear in-plane order (θ=0\theta=0 with an error of \sim 5^{\circ}). Comparison with scanning tunnelling microscopy on a series of Fe1+x_{1+x}Te samples reveals that the surface exhibits a magnetic surface reconstruction with a canting angle of the spins of θ=29.8\theta=29.8^{\circ}. We suggest that this is a consequence of structural relaxation of the surface layer resulting in an out-of-plane magnetocrystalline anisotropy. The magnetism in Fe1+x_{1+x}Te displays different properties at the surface when the symmetry constraints of the bulk are removed.

Keywords

Cite

@article{arxiv.2101.00569,
  title  = {Magnetic surface reconstruction in the van-der-Waals antiferromagnet Fe$_{1+x}$Te},
  author = {C. Trainer and M. Songvilay and N. Qureshi and A. Stunault and C. M. Yim and E. E. Rodriguez and C. Heil and V. Tsurkan and M. A. Green and A. Loidl and P. Wahl and C. Stock},
  journal= {arXiv preprint arXiv:2101.00569},
  year   = {2021}
}

Comments

11 pages, 6 figures, to be Published in Phys. Rev. B