English

Magnetic structures of geometrically frustrated SrGd$_2$O$_4$ derived from powder and single-crystal neutron diffraction

Strongly Correlated Electrons 2022-02-02 v1

Abstract

We present the low-temperature magnetic structures of SrGd2_2O4_4 combining neutron diffraction methods on polycrystalline and single-crystal samples containing the 160^{160}Gd isotope. In contrast to other members of the SrLn2Ln_2O4_4 family (LnLn = lanthanide) this system reveals two long-range ordered magnetic phases, which our diffraction data unambiguously identify. Below TN1T_{\rm N1} = 2.73~K, a q1\mathbf{q}_1 = (0 0 0) magnetic structure is stabilized where ferromagnetic chains along the cc~axis (space group PnamPnam) are coupled antiferromagnetically with neighboring chains. On cooling below TN2T_{\rm N2} = 0.48~K, an additional incommensurate component modulated by q2\mathbf{q}_2 = (0~0~0.42) evolves and aligned along either of the perpendicular axes for the two different Gd sites, resulting in a fan-like magnetic structure. The identification of the particular Gd sites with the magnetic order observed with neutron diffraction is facilitated by a detailed analysis of the crystal fields acting on the sites. The observed ordering phenomena underline the complex multiaxial anisotropy in this system.

Keywords

Cite

@article{arxiv.2201.01176,
  title  = {Magnetic structures of geometrically frustrated SrGd$_2$O$_4$ derived from powder and single-crystal neutron diffraction},
  author = {N. Qureshi and B. Z. Malkin and S. X. M. Riberolles and C. Ritter and B. Ouladdiaf and G. Balakrishnan and M. Ciomaga Hatnean and O. A. Petrenko},
  journal= {arXiv preprint arXiv:2201.01176},
  year   = {2022}
}