English

Magnetic frustration and weak Mn magnetic ordering in EuMn$_2$P$_2$

Strongly Correlated Electrons 2025-01-03 v1

Abstract

We report on the electron spin resonance (ESR), heat capacity, magnetization, nuclear magnetic resonance (NMR), magnetic circular and linear dichroism (XMCD, XMLD), as well as the electrical resistivity of EuMn2_{2}P2_{2} single crystals. Antiferromagnetic order of Eu was observed in several quantities at TNEu=18KT^{\rm Eu}_{\rm N}\,=\,18\,\rm K. The temperature dependencies of ESR linewidth and resonance shift show, when approaching the Eu-ordered state, a divergence towards TNEuT^{\rm Eu}_{\rm N}, indicating the growing importance of magnetic correlations and the build-up of internal magnetic fields. An additional temperature scale of 47K\approx 47\,\rm K has considerable impact on linewidth, resonance field and intensity. This points to the presence of weak Mn-based ordering. The observed ESR line is interpreted as an Eu2+^{2+} resonance, which probes the weak magnetic background of the Mn subsystem. Such picture is suggested by the lineshape which keeps to be Lorentzian across the 47K47\,\rm K scale and by the ESR intensity which can be described by the same Curie-Weiss temperature above and below 47K47\,\rm K. In the same temperature range anomalies were observed at 48.5K48.5\,\rm K and 51K51\,\rm K in the heat capacity data as well as a pronounced broadening of the NMR signal of the EuMn2_{2}P2_{2} samples. In XMCD and XMLD measurements, this weak magnetic order could not be detected in the same temperature range which might be due to the small magnetic moment, with a potential cc-component or frustration.

Keywords

Cite

@article{arxiv.2501.01355,
  title  = {Magnetic frustration and weak Mn magnetic ordering in EuMn$_2$P$_2$},
  author = {Sarah Krebber and Jörg Sichelschmidt and Pierre Chailloleau and Asmaa El Mard and Marvin Kopp and Michael Baenitz and Kurt Kummer and Denis V. Vyalikh and Jens Müller and Cornelius Krellner and Kristin Kliemt},
  journal= {arXiv preprint arXiv:2501.01355},
  year   = {2025}
}